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Resins

Working Safely With Resins (Notes from Jenny Lee)

Note: the ITP shop is not properly ventilated for working with resins. Never do resin work at ITP. Always work in a properly ventilated space elsewhere.
The Compleat Sculptor offers some great classes on working with resins and other sculpting materials.

There are a number of things to consider:

  • What resin are you working with?
  • Does it involve fibreglas or anything that has the potential of generating particulates?
  • Do you have engineering controls in your environment; eg., ventilation?

To find out the chemical contents and the potential hazards of the resins you are working with, look up the MSDS - Material Safety Data Sheets. Available at:

Cornell U. has acomprehensive site

The national MSDS site is also valuable

A mirror of this site is here.

Then you want to get a respirator - most likely a half-mask, that fits you. 3M, AO, North are good brands

A respirator requires cartridges and accessories specific to the chemical content of your materials: VOC (Volatile Organic Content) like an N 95 cartridge, for the resin fumes, a cotton filter for the particulates (if there's fibreglas)

Respirator cartridges have a life-span. Once they expire, they will no longer be effective.

Respirators have to fit. They usually come in sizes: S, M, L. You also should not have facial hair for respirators to be effective.

There is currently NO protection for Urethanes. Make sure the room is well ventilated and the air is blowing away from you.

Please be very careful and respectful of the potential hazards associated with resins. Below are some notes which may be helpful.

Safety Equipment

Respirators

Respirators are among the most important pieces of protective equipment for working in hazardous environments. Selecting the right respirator requires an assessment of all the workplace operations, processes or environment that may create a respiratory hazard. The identity of the hazard and its airborne concentrations need to be determined before choosing a respirator. This assessment should be done by experienced safety personnel or by an industrial hygienist.

Several agencies are responsible for researching and establishing contaminant exposure limit levels for hazardous substances. The American Conference of Governmental Industrial Hygienists (ACGIH) is a voluntary organization of safety professionals that develops and reviews exposure limit values. ACGIH results are based on animal, human and industrial studies. The National Institute for Occupational Safety and Health (NIOSH) is a federal agency that conducts research on safety and health concerns. NIOSH is responsible for developing and revising recommended exposure limits for hazardous substances. The recommendations are then transmitted to the Occupational Safety and Health Administration (OSHA), a federal agency in the Department of Labor which has safety, regulatory and enforcement authority over most industry and business.

Respirator Type

Once a workplace assessment has been completed and engineering controls have been ruled out, the respirator selection process can begin. There are several different respirators for various hazard situations. The respirator you choose should provide protection against the hazard for which it was designed, in addition to being NIOSH approved.

Air-purifying respirators can be either full-face or half masks with mechanical or chemical cartridges to filter dusts, mists, fumes, vapors or gases. They are available in three types: disposable, reusable, and disposable/reusable.

Disposable air-purifying respirators are intended to be used once or until the cartridge expires. The cartridges are permanently attached and have no replacement parts. Reusable air-purifying respirators use both replaceable cartridges and parts. NOTE: The replaceable cartridges and parts must be from the same manufacturer to retain a NIOSH approval. Disposable/reusable air-purifying respirators have no replaceable parts except cartridges.

Gas masks are designed for slightly higher concentrations of organic vapors, gases, dusts, mists and fumes. The volume of sorbent used as the medium is higher than a chemical cartridge.

Powered air-purifying respirators use a blower to pass the contaminated air through a filter. The purified air is then delivered into a mask or hood. They filter dusts, mists, fumes, vapors and gases, just like ordinary air-purifying respirators.

Air-purifying respirators cannot be used in oxygen-deficient atmospheres, which can result when another gas displaces the oxygen or consumption of oxygen by a chemical reaction occurs. Oxygen levels below 19.5% require either a source of supplied air or supplied-air respirator protection. Levels below 16% are considered to be unsafe and could cause death.

Supplied-air respirators provide the highest level of protection against highly toxic and unknown materials. Supplied air refers to self-contained breathing apparatuses (SCBAs) and air-line respirators. SCBAs have a limited air supply that is carried by the user, allowing for good mobility and fewer restrictions than air-line respirators.

Air-line respirators have an air hose that is connected to a fresh air supply from a central source. The source can be from a compressed air cylinder or air compressor that provides at least Grade D breathing air.

Emergency Escape Breathing Apparatuses (EEBAs) provide oxygen for 5, 10 or 15 minutes depending on the unit. These are for emergency situations in which a worker must escape from environments immediately dangerous to life or health (IDLH).

Material Types

Respirators can be made from a variety of materials. The most popular facepiece materials are silicone, neoprene, and rubber. In general, rubber and neoprene are rigid, durable materials. Silicone is preferred for its comfort, flexibility and ease in cleaning. Full-face respirators are available with six-strap harnesses or ratchet suspensions. The harness type can be worn with a hard hat, but ratchet suspensions are generally easier to adjust, making donning and doffing easier.

Optional Features

Various features are available to help you customize respirators to suit your employees and the specific hazards they encounter. For example, nose cups reduce lens fogging and lens covers protect the lens from paint, minor chemical splash and scratches.

Spectacle kits are needed when using prescription corrective lenses. The frame mounts into full-face masks, and the prescription lenses are made by the wearers' optometrist. This allows the wearer to maintain a proper fit and still wear prescription lenses.

Cartridge Types

To determine the proper cartridge for air-purifying respirators, either contact a safety professional or consult the Material Safety Data Sheet of the substance that needs to be filtered. All cartridges are assigned a color designating the type of contaminant they will filter:

Cartridge Color: Contaminant

  • White: Acid gas
  • Black: Organic vapors
  • Green: Ammonia gas
  • Yellow: Acid gas and organic vapors
  • Purple: Radioactive materials
  • Orange: Dust, fumes and mists
  • Olive: Other gases and vapors

The medium used as the filter is usually activated carbon. The adsorption capacity of the filter is limited. Once the wearer of the respirator can detect an odor, irritation, or taste of the contaminant, the cartridge should be replaced.

Particulate Filter Classification

In July of 1995, NIOSH published a final rule that replaced current MSHA regulations with new public health regulations. NIOSH also upgraded test requirements for the certification of particulate filters. More filters are now meeting these test requirements, giving you a greater selection to choose from. These filters also meet the criteria set by the Centers for Disease Control (CDC) for protection against Tuberculosis.

The nine classes of filters are broken down into three series: N, R, and P. Each series has three efficiency levels: 95%, 99%, and 99.97%. The efficiency levels are determined by testing the filter with either sodium chloride (NaCl) or dioctyl phthalate (DOP) until a maximum load of 200 mg is reached. Sodium chloride is a mildly degrading material, while dioctyl phthalate is highly degrading. The difference between the three series of filters is found in their limitations and the way they are tested.

The N series filter is tested with NaCl, and is used in environments free of oil aerosols. The R series is tested with DOP. A respirator with this series filter should only be worn for one work shift. The P filter is also tested with DOP, but the test doesn't stop at a 200 mg load. The test continues until there is no further decrease in efficiency at the 95%, 99%, or 99.97% level.

Fit Testing

Employers are required to fit test any employee who needs to wear a respirator. This includes dust/mist respirators. Fit testing is a requirement of 29 CFR 1910.134

Written Program

Any time a respirator is used in the workplace, a written program must be established. A program outlines very specific procedures for respirator use in all situations. The program can vary in format, but must contain specific information on topics ranging from buying a respirator to employee training.

Ongoing workplace monitoring ensures that employees are adequately protected. Any change in the workplace operations may change the levels of contaminants or introduce new hazards. If a change occurs, the entire respirator program should be re-evaluated to determine its effectiveness.

Commonly Asked Questions

Q. What are nuisance levels?

A. Nuisance levels refer to concentrations of contaminants below the OSHA Permissible Exposure Level.

Q. What is the shelf life of a cartridge?

A. Cartridges have an indefinite shelf life, unless otherwise specified by the manufacturer.

Q. What does HEPA stand for?

A. High Efficiency Particulate Absolute. HEPA filters remove from air 99.97% or more of particles having a diameter of 0.3 microns.

Sources for More Information

29 CFR 1910.134, Respiratory Protection.

29 CFR 1910.1000, Air Contaminants Standard.

American National Standards Institute
11 W. 42nd Street
New York, NY 10036

ANSI Z88.2-1992, American National Standard for Respiratory Protection.

Blackwell, Daid S., Rajhans, Practical Guide to Respiratory Usage in Industry, Boston, 1985.

Hansen, Doan J., The Work Environment. Occupational Health Fundamentals, Chelsea, 1991, pp. 304--308.

Plog, Barbara A., Fundamentals of Industrial Hygiene, National Safety Council, 1988, pp.521--568.

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